Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-imidazole}sulfatomanganese(II) dihydrate
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چکیده
In the title complex, [Mn(SO(4))(C(10)H(9)N(5))(H(2)O)(4)]·2H(2)O, the Mn(2+) cation is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-imidazole ligand and five O atoms from one monodentate sulfate ligand and four water mol-ecules in a distorted octa-hedral geometry. In the crystal, adjacent mol-ecules are linked through O-H⋯O and O-H⋯N hydrogen bonds into a three-dimensional network.
منابع مشابه
Tetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatocadmium dihydrate
In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol-ecules and one monodentate sulfate anion in a distorted octa-hedral geometry. The sulfate tetra-hedron is rotationally disordered over two positions in a 0.651 (12):0.349 ...
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In the title complex, [Co(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Co(II) ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water mol-ecules in a slightly distorted octa-hedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of ...
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In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water mol-ecules in a distorted octa-hedral geometry. The sulfate tetra-hedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19...
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In the title mononuclear complex, [CoCl(2)(C(11)H(11)N(5))(2)], the Co(II) atom is four-coordinated by two ligand N atoms and two Cl atoms in a distorted tetra-hedral geometry. In the crystal, mol-ecules are stacked through π-π inter-actions [centroid-centroid distances = 3.473 (2), 3.807 (3), 3.883 (2) and 3.676 (2) Å], forming a three-dimensional supra-molecular network.
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In the mononuclear title compound, [ZnCl(2)(C(11)H(11)N(5))(2)], the Zn(II) atom is coordinated by two Cl atoms and two imidazole N atoms in a distorted tetra-hedral geometry. Adjacent complex mol-ecules are stacked through aromatic π-π inter-actions; the closest distance between adjacent aromatic rings is 3.598 (2) Å.
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